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What are the different classes of Dangerous goods?

The Nine Classes of Dangerous Goods
Class Sub class Symbol Description Examples

Class 1

Explosives

 Class 1.1 – Explosives with a mass explosion

hazard such as TNT, Gunpowder. Gelignite,

etc.

Class

These materials will explode. These are covered by the Australian Code for the Transportation of Explosives by Road and Rail (Australian Explosives Code).

TNT

ANFO

nitroglycerine

 

Class 1.2 – Explosives which are a projectile

or fragmentation hazard, but not a significant

mass explosion hazard .

Class

 

grenades,

ammunition, etc

 

Class 1.3 – Explosives which are a fire and minor blast hazard, with minor projectile or minor fragmentation hazards.

Class

 

propellant powder, fireworks

 

Class 1.4 – Explosives which are not a

significant mass explosion hazard

Class

 

flares,

fireworks, safety cartridges, etc.

 

Class 1.5 – Explosives with a mass explosion

hazard, but are insensitive substances

Class

   
 

Class 1.6 – Substances which are a minor

explosion hazard, very insensitive substances.

Class 1.6

   

Class 2

Gases

Class 2.1

Flammable gases

Class

These are gases which will burn.

acetylene

hydrogen

LPG

Class 2.2

Non-flammable

non-toxic gases

Class

Class

These gases are usually compressed and so are a source of stored energy and some may also present an anoxic hazard (that is, they will exclude oxygen and so kill through asphyxiation). These containers may rocket if valves are damaged or containers are involved in a fire.

air

carbon dioxide

nitrogen

Class 2.3

Poisonous gas

Class

These gases are toxic. Being gases, they will rapidly disperse if there is a leak. This may reduce the concentration and the hazard - but it will also spread the gas further, so increasing the risk of poisoning more people.

chlorine

methyl bromide

nitric oxide

Class 3

Flammable liquids

Class

These liquids will all burn.

petrol

kerosene

Class 4

Flammable solids

Class 4.1

Flammable solids, self-reactive and related substances and desensitised explosives

Class

Solids easily ignited and readily combustible. These are ordinarily flammable solids which don't fit into Class 4.2 or 4.3.

sulfur

phosphorus

picric acid

Class 4.2

Spontaneously combustible

Class

These materials will catch fire if exposed to air without any heat being applied (that is, the heat from the normal air is sufficient for them to catch fire - no other source of heat is required).

charcoal (non-activated)

Class 4.3

Dangerous when wet

Class

This class is also known as 'Emits flammable gases when wet'. This class has a particular hazard: not only can moisture from the air cause a fire, but if water or foam is used to extinguish them, it will make the situation worse.

calcium carbide

Class 5

Oxidising substances

Class 5.1

Oxidising agent

Class

These are all oxidising agents other than organic peroxides. When substances burn in air, they combine with oxygen and so are said to have been oxidised. Other chemicals have a similar 'burning' effect and so are said to be oxidising agents. The largest group of these is the organic peroxides.

chlorine

calcium hypochlorite

sodium peroxide

Class 5.2

Organic peroxides

(liquid or solid)

Class

These are a particular class of oxidising agent. They have all the normal hazards of oxidising agents (that is, they will cause a 'chemical burning'). In addition, they will often be explosive under certain conditions - especially, if they are allowed to dry out.

benzoyl peroxides

methyl ethyl

ketone peroxides (MEKP)

Class 6

Poisonous and infectious substances

Class 6.1a

Poisons

Class

These are liable to cause death or serious injury to human health if inhaled, swallowed or absorbed through the skin. They are covered by special regulations and need special registration. It is acceptable to use the word 'toxic' to replace the word 'poison'.

cyanides

lead

arsenic

Class 6.1b

Harmful

 

These are materials which must be stored away from food stuffs but which are not classified as poisons.

pesticides

heavy metals

Class 6.2

Infectious substances

Class

Substances containing viable micro-organisms that may cause disease in humans or animals.

diagnostic specimens or live vaccines

Class 7

Radio active substances

DGC7

DGC71

DGC72

DGC73

Materials or combinations of materials which spontaneously emit ionising radiation.

These materials are covered by the Code of Practice for the Safe Transport of Radioactive Substances, 1990.

uranium

radio isotopes

plutonium

Class 8

Corrosives

Class

These chemicals will eat away at a wide range of materials including some materials of construction for tanks and probably your eyes and skin.

Care must be taken to ensure the containers and packages are made from the right materials and the chemicals do not contact your clothes, skin or eyes.

Special protective equipment needs to be worn.

hydrochloric acid

sodium hypochlorite (liquid pool chlorine)

sodium hydroxide (caustic soda)

Class 9

Miscellaneous goods

Class

Substances and articles which have potentially dangerous properties that are relatively minor, or are not covered by any of the classes already described.

aerosols

polyester beads

Mixed class label

symbolmixed

This class label is used whenever more than one class of Dangerous Goods is being carried in the one load, and the vehicle requires marking.


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